An optically reversible room-temperature solid-state cobalt( iii ) photoswitch based on nitro-to-nitrito linkage isomerism - Université de Lorraine Access content directly
Journal Articles Chemical Communications Year : 2022

An optically reversible room-temperature solid-state cobalt( iii ) photoswitch based on nitro-to-nitrito linkage isomerism

Krystyna Deresz
Radosław Kamiński
Katarzyna Jarzembska

Abstract

The first transition-metal nitro complex that exhibits optically reversible room-temperature photoswitchability with notable nitro-to-nitrito conversion of ca. 55% is reported.
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hal-03897610 , version 1 (31-01-2024)

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Krystyna Deresz, Radosław Kamiński, Sylwia Kutniewska, Adam Krówczyński, Dominik Schaniel, et al.. An optically reversible room-temperature solid-state cobalt( iii ) photoswitch based on nitro-to-nitrito linkage isomerism. Chemical Communications, 2022, 58 (97), pp.13439-13442. ⟨10.1039/D2CC05134F⟩. ⟨hal-03897610⟩
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