Etude expérimentale et modélisation de la décomposition thermique de l'exo-tricyclo [5.2.1.0 2,6] décane :

Abstract : The thermal decomposition of the exo-tricyclo [5.2.1.0 2,6] decane, a tricyclic alkane which is part of some fuels used in aeronautics, was studied at the DCPR in the scope of the development of the cooling system of the engine of hypersonic aircrafts. The experimental study of the thermal decomposition of this alkane was performed with a jet stirred reactor, at atmospheric pressure, at high dilution, at residence times between 0.5 and 6s and for a wide range of temperatures (673-1173 K). The formation of 53 products of the reaction was observed during this study. A mechanism of the pyrolysis of the exo-tricyclo [5.2.1.0 2,6] decane was developed (2789 reactions ; 929 molecular, radical et biradical species) and was validated from experimental results. The kinetic analysis of the mechanism highlighted the importance of the reactions of unimolecular initiation on the consumption of the reactant
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Olivier Herbinet. Etude expérimentale et modélisation de la décomposition thermique de l'exo-tricyclo [5.2.1.0 2,6] décane :. Autre. Institut National Polytechnique de Lorraine, 2006. Français. ⟨NNT : 2006INPL049N⟩. ⟨tel-01752479⟩

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