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Synthesis, properties and applications of itaconate based engineering elastomers

Abstract : This thesis deals with the preparation and application of itaconate based engineering elastomers and their nanocomposites. The following elastomers or nanocomposites were prepared: (1) nanocomposites based on 3,9-bis[1,1-dim ethyl-2-{b-(3-tertbutyl-4-hydroxy-5-methylphenyl)propionyloxy}ethyl]-2,4,8,10-tetraoxaspiro-[5,5]-undecane (AO-80) and poly(diisoamyl itaconate-co-isoprene) (PDII), (2) a bio-based carboxylic elastomer, poly(dibutyl itaconate-co-isoprene-co-methacrylic acid) (PDIM), and nanocomposites based on it and silica or halloysite nanotubes, (3) a novel bio-based elastomer, poly(dibutyl itaconate-co-butadiene) (PDIB), and nanocomposites based on it and silica. Bio-based green tires were manufactured by using PDIB/silica nanocomposite in a tire tread formulation. In addition to the preparation of the above bio-based elastomers and their nanocomposites, this thesis also gives a review on the progresses on bio-inspired sacrificial bonds in polymeric materials. This review will serve as a guide to engineer sacrificial bonds into itaconate based elastomers with high strength and toughness
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Submitted on : Tuesday, November 13, 2018 - 9:08:48 AM
Last modification on : Wednesday, November 3, 2021 - 7:09:17 AM

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  • HAL Id : tel-01920194, version 1



Xinxin Zhou. Synthesis, properties and applications of itaconate based engineering elastomers. Chemical and Process Engineering. Université de Lorraine; Beijing University of Chemical Technology (Chine), 2018. English. ⟨NNT : 2018LORR0006⟩. ⟨tel-01920194⟩



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